Structural forms in complexes of 2,9-dimethyl-1,10-phenanthroline with simple salts of copper(I) and other univalent 'closed shell' species

Siti Mutrofin; Eric J. Chan; Peter C. Healy; Alessandro Marinelli; Jean Ngoune; Claudio Pettinari; Riccardo Pettinari; Neil Somers; Brian W. Skelton; Allan H. White

doi:10.1016/j.ica.2007.11.009

Structural forms in complexes of 2,9-dimethyl-1,10-phenanthroline with simple salts of copper(I) and other univalent 'closed shell' species

Siti Mutrofin
, Eric J. Chan
, Peter C. Healy
, Alessandro Marinelli
, Jean Ngoune
, Claudio Pettinari^*
, Riccardo Pettinari
, Neil Somers
, Brian W. Skelton
, Allan H. White

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Syntheses, spectroscopic and structural characterizations of a series of Cu(I)-phenanthroline complexes are reported. A single crystal X-ray structure determination is recorded for CuNO₃:dmp:MeCN (1:1:1), 'dmp' = 2,9-dimethyl-1,10-phenanthroline, showing it to be isomorphous with its previously studied tetrafluoroborate, perchlorate and hexafluorophosphate, and silver(I) perchlorate counterparts, the metal atom lying in a trigonal planar [(N^∧N)Cu(NCMe)] coordination environment, the anion not being coordinated. Structure (re-) determinations are also reported for a number of salts of the [Cu(dmp)₂]⁺ cation: the perchlorate, isomorphous with numerous other salts, not only of copper(I), but also lithium(I)), also the unsolvated nitrate, and a solvated form of the chloride.

Original language	English
Pages (from-to)	2365-2374
Number of pages	10
Journal	Inorganica Chimica Acta
Volume	361
Issue number	8
DOIs	https://doi.org/10.1016/j.ica.2007.11.009
Publication status	Published - 2 Jun 2008
Externally published	Yes

Keywords

2,9-Dimethyl-1,10-phenanthroline
Copper(I) complexes
X-ray crystal structure

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10.1016/j.ica.2007.11.009

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Mutrofin, S., Chan, E. J., Healy, P. C., Marinelli, A., Ngoune, J., Pettinari, C., Pettinari, R., Somers, N., Skelton, B. W., & White, A. H. (2008). Structural forms in complexes of 2,9-dimethyl-1,10-phenanthroline with simple salts of copper(I) and other univalent 'closed shell' species. Inorganica Chimica Acta, 361(8), 2365-2374. https://doi.org/10.1016/j.ica.2007.11.009

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title = "Structural forms in complexes of 2,9-dimethyl-1,10-phenanthroline with simple salts of copper(I) and other univalent 'closed shell' species",

abstract = "Syntheses, spectroscopic and structural characterizations of a series of Cu(I)-phenanthroline complexes are reported. A single crystal X-ray structure determination is recorded for CuNO3:dmp:MeCN (1:1:1), 'dmp' = 2,9-dimethyl-1,10-phenanthroline, showing it to be isomorphous with its previously studied tetrafluoroborate, perchlorate and hexafluorophosphate, and silver(I) perchlorate counterparts, the metal atom lying in a trigonal planar [(N∧N)Cu(NCMe)] coordination environment, the anion not being coordinated. Structure (re-) determinations are also reported for a number of salts of the [Cu(dmp)2]+ cation: the perchlorate, isomorphous with numerous other salts, not only of copper(I), but also lithium(I)), also the unsolvated nitrate, and a solvated form of the chloride.",

keywords = "2,9-Dimethyl-1,10-phenanthroline, Copper(I) complexes, X-ray crystal structure",

author = "Siti Mutrofin and Chan, \{Eric J.\} and Healy, \{Peter C.\} and Alessandro Marinelli and Jean Ngoune and Claudio Pettinari and Riccardo Pettinari and Neil Somers and Skelton, \{Brian W.\} and White, \{Allan H.\}",

year = "2008",

month = jun,

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doi = "10.1016/j.ica.2007.11.009",

language = "English",

volume = "361",

pages = "2365--2374",

journal = "Inorganica Chimica Acta",

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TY - JOUR

T1 - Structural forms in complexes of 2,9-dimethyl-1,10-phenanthroline with simple salts of copper(I) and other univalent 'closed shell' species

AU - Mutrofin, Siti

AU - Chan, Eric J.

AU - Healy, Peter C.

AU - Marinelli, Alessandro

AU - Ngoune, Jean

AU - Pettinari, Claudio

AU - Pettinari, Riccardo

AU - Somers, Neil

AU - Skelton, Brian W.

AU - White, Allan H.

PY - 2008/6/2

Y1 - 2008/6/2

N2 - Syntheses, spectroscopic and structural characterizations of a series of Cu(I)-phenanthroline complexes are reported. A single crystal X-ray structure determination is recorded for CuNO3:dmp:MeCN (1:1:1), 'dmp' = 2,9-dimethyl-1,10-phenanthroline, showing it to be isomorphous with its previously studied tetrafluoroborate, perchlorate and hexafluorophosphate, and silver(I) perchlorate counterparts, the metal atom lying in a trigonal planar [(N∧N)Cu(NCMe)] coordination environment, the anion not being coordinated. Structure (re-) determinations are also reported for a number of salts of the [Cu(dmp)2]+ cation: the perchlorate, isomorphous with numerous other salts, not only of copper(I), but also lithium(I)), also the unsolvated nitrate, and a solvated form of the chloride.

AB - Syntheses, spectroscopic and structural characterizations of a series of Cu(I)-phenanthroline complexes are reported. A single crystal X-ray structure determination is recorded for CuNO3:dmp:MeCN (1:1:1), 'dmp' = 2,9-dimethyl-1,10-phenanthroline, showing it to be isomorphous with its previously studied tetrafluoroborate, perchlorate and hexafluorophosphate, and silver(I) perchlorate counterparts, the metal atom lying in a trigonal planar [(N∧N)Cu(NCMe)] coordination environment, the anion not being coordinated. Structure (re-) determinations are also reported for a number of salts of the [Cu(dmp)2]+ cation: the perchlorate, isomorphous with numerous other salts, not only of copper(I), but also lithium(I)), also the unsolvated nitrate, and a solvated form of the chloride.

KW - 2,9-Dimethyl-1,10-phenanthroline

KW - Copper(I) complexes

KW - X-ray crystal structure

UR - https://www.scopus.com/pages/publications/43949095465

U2 - 10.1016/j.ica.2007.11.009

DO - 10.1016/j.ica.2007.11.009

M3 - Article

AN - SCOPUS:43949095465

SN - 0020-1693

VL - 361

SP - 2365

EP - 2374

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 8

ER -

Structural forms in complexes of 2,9-dimethyl-1,10-phenanthroline with simple salts of copper(I) and other univalent 'closed shell' species

Abstract

Keywords

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