Effect of grafting-intercalation combination toward delamination of kaoline

Tutik Setianingsih; Danar Purwonugroho; Siti Mutrofin; Tengku Nurul Rohma; Tutik Setianingsih

doi:10.1063/5.0071553

Effect of grafting-intercalation combination toward delamination of kaoline

Tutik Setianingsih^*
, Danar Purwonugroho
, Siti Mutrofin
, Tengku Nurul Rohma
, Tutik Setianingsih^*

^*Corresponding author for this work

Faculty of Mathematics and Natural Sciences

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

1 Citation (Scopus)

Abstract

Kaoline is one of natural clays. This layered mineral can be delaminated, i.e separation of layers of kaoline each other. To achieve the purpose, kaoline can be grafted or intercalated. In this research, kaoline was treated by both combination. Sequaence of treatments (intercalation-grafting and grafting-intercalation) were studied in this research. Propanol and sodium dodesyl benzene sulphonate (SDBS) surrfactant were used for grafting and intercalation process, respectively. Before those treatments, activation of kaoline was performed by stirring of kaoline in H2SO4 solution (0.1M). The activated kaoline was intercalated by SDBS solution (0.1M) statically followed by under stirring, then grafted by propanol statically followed by under stirring. The opposite treatment was the grafting by propanol statically followed by under stirring, then intercalated statically followed by under stirring. Characterization using FTIR spectrometry shows that the grafting treatment gave no significant difference, but intercalation treatment gave significant changing of FTIR spectra, especially related to C-H bond vibration, connected to surfactant. SEM characterization confirmed that the treatment of the intercalation-grafting provided more delaminated kaoline than the grafting-intercalation.

Original language	English
Title of host publication	4th International Conference on Materials and Metallurgical Engineering and Technology, ICOMMET 2020
Editors	Mas Irfan Purbawanto Hidayat, Amaliya Rasyida
Publisher	American Institute of Physics Inc.
ISBN (Electronic)	9780735441743
DOIs	https://doi.org/10.1063/5.0071553
Publication status	Published - 30 Dec 2021
Event	4th International Conference on Materials and Metallurgical Engineering and Technology, ICOMMET 2020 - Surabaya, Indonesia Duration: 19 Oct 2020 → …

Publication series

Name	AIP Conference Proceedings
Volume	2384
ISSN (Print)	0094-243X
ISSN (Electronic)	1551-7616

Conference

Conference	4th International Conference on Materials and Metallurgical Engineering and Technology, ICOMMET 2020
Country/Territory	Indonesia
City	Surabaya
Period	19/10/20 → …

Keywords

Delamination
Grafting
intercalation
Kaoline

Access to Document

10.1063/5.0071553

Cite this

Setianingsih, T., Purwonugroho, D., Mutrofin, S., Rohma, T. N., & Setianingsih, T. (2021). Effect of grafting-intercalation combination toward delamination of kaoline. In M. I. P. Hidayat, & A. Rasyida (Eds.), 4th International Conference on Materials and Metallurgical Engineering and Technology, ICOMMET 2020 Article 050009 (AIP Conference Proceedings; Vol. 2384). American Institute of Physics Inc.. https://doi.org/10.1063/5.0071553

Setianingsih, Tutik ; Purwonugroho, Danar ; Mutrofin, Siti et al. / Effect of grafting-intercalation combination toward delamination of kaoline. 4th International Conference on Materials and Metallurgical Engineering and Technology, ICOMMET 2020. editor / Mas Irfan Purbawanto Hidayat ; Amaliya Rasyida. American Institute of Physics Inc., 2021. (AIP Conference Proceedings).

@inproceedings{fc27e5948b514651906a8c54980a3289,

title = "Effect of grafting-intercalation combination toward delamination of kaoline",

abstract = "Kaoline is one of natural clays. This layered mineral can be delaminated, i.e separation of layers of kaoline each other. To achieve the purpose, kaoline can be grafted or intercalated. In this research, kaoline was treated by both combination. Sequaence of treatments (intercalation-grafting and grafting-intercalation) were studied in this research. Propanol and sodium dodesyl benzene sulphonate (SDBS) surrfactant were used for grafting and intercalation process, respectively. Before those treatments, activation of kaoline was performed by stirring of kaoline in H2SO4 solution (0.1M). The activated kaoline was intercalated by SDBS solution (0.1M) statically followed by under stirring, then grafted by propanol statically followed by under stirring. The opposite treatment was the grafting by propanol statically followed by under stirring, then intercalated statically followed by under stirring. Characterization using FTIR spectrometry shows that the grafting treatment gave no significant difference, but intercalation treatment gave significant changing of FTIR spectra, especially related to C-H bond vibration, connected to surfactant. SEM characterization confirmed that the treatment of the intercalation-grafting provided more delaminated kaoline than the grafting-intercalation.",

keywords = "Delamination, Grafting, intercalation, Kaoline",

author = "Tutik Setianingsih and Danar Purwonugroho and Siti Mutrofin and Rohma, \{Tengku Nurul\} and Tutik Setianingsih",

note = "Publisher Copyright: {\textcopyright} 2021 Author(s).; 4th International Conference on Materials and Metallurgical Engineering and Technology, ICOMMET 2020 ; Conference date: 19-10-2020",

year = "2021",

month = dec,

day = "30",

doi = "10.1063/5.0071553",

language = "English",

series = "AIP Conference Proceedings",

publisher = "American Institute of Physics Inc.",

editor = "Hidayat, \{Mas Irfan Purbawanto\} and Amaliya Rasyida",

booktitle = "4th International Conference on Materials and Metallurgical Engineering and Technology, ICOMMET 2020",

}

Setianingsih, T , Purwonugroho, D , Mutrofin, S, Rohma, TN & Setianingsih, T 2021, Effect of grafting-intercalation combination toward delamination of kaoline. in MIP Hidayat & A Rasyida (eds), 4th International Conference on Materials and Metallurgical Engineering and Technology, ICOMMET 2020., 050009, AIP Conference Proceedings, vol. 2384, American Institute of Physics Inc., 4th International Conference on Materials and Metallurgical Engineering and Technology, ICOMMET 2020, Surabaya, Indonesia, 19/10/20. https://doi.org/10.1063/5.0071553

Effect of grafting-intercalation combination toward delamination of kaoline. / Setianingsih, Tutik ; Purwonugroho, Danar ; Mutrofin, Siti et al.
4th International Conference on Materials and Metallurgical Engineering and Technology, ICOMMET 2020. ed. / Mas Irfan Purbawanto Hidayat; Amaliya Rasyida. American Institute of Physics Inc., 2021. 050009 (AIP Conference Proceedings; Vol. 2384).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Effect of grafting-intercalation combination toward delamination of kaoline

AU - Setianingsih, Tutik

AU - Purwonugroho, Danar

AU - Mutrofin, Siti

AU - Rohma, Tengku Nurul

AU - Setianingsih, Tutik

PY - 2021/12/30

Y1 - 2021/12/30

N2 - Kaoline is one of natural clays. This layered mineral can be delaminated, i.e separation of layers of kaoline each other. To achieve the purpose, kaoline can be grafted or intercalated. In this research, kaoline was treated by both combination. Sequaence of treatments (intercalation-grafting and grafting-intercalation) were studied in this research. Propanol and sodium dodesyl benzene sulphonate (SDBS) surrfactant were used for grafting and intercalation process, respectively. Before those treatments, activation of kaoline was performed by stirring of kaoline in H2SO4 solution (0.1M). The activated kaoline was intercalated by SDBS solution (0.1M) statically followed by under stirring, then grafted by propanol statically followed by under stirring. The opposite treatment was the grafting by propanol statically followed by under stirring, then intercalated statically followed by under stirring. Characterization using FTIR spectrometry shows that the grafting treatment gave no significant difference, but intercalation treatment gave significant changing of FTIR spectra, especially related to C-H bond vibration, connected to surfactant. SEM characterization confirmed that the treatment of the intercalation-grafting provided more delaminated kaoline than the grafting-intercalation.

AB - Kaoline is one of natural clays. This layered mineral can be delaminated, i.e separation of layers of kaoline each other. To achieve the purpose, kaoline can be grafted or intercalated. In this research, kaoline was treated by both combination. Sequaence of treatments (intercalation-grafting and grafting-intercalation) were studied in this research. Propanol and sodium dodesyl benzene sulphonate (SDBS) surrfactant were used for grafting and intercalation process, respectively. Before those treatments, activation of kaoline was performed by stirring of kaoline in H2SO4 solution (0.1M). The activated kaoline was intercalated by SDBS solution (0.1M) statically followed by under stirring, then grafted by propanol statically followed by under stirring. The opposite treatment was the grafting by propanol statically followed by under stirring, then intercalated statically followed by under stirring. Characterization using FTIR spectrometry shows that the grafting treatment gave no significant difference, but intercalation treatment gave significant changing of FTIR spectra, especially related to C-H bond vibration, connected to surfactant. SEM characterization confirmed that the treatment of the intercalation-grafting provided more delaminated kaoline than the grafting-intercalation.

KW - Delamination

KW - Grafting

KW - intercalation

KW - Kaoline

UR - https://www.scopus.com/pages/publications/85144069099

U2 - 10.1063/5.0071553

DO - 10.1063/5.0071553

M3 - Conference contribution

AN - SCOPUS:85144069099

T3 - AIP Conference Proceedings

BT - 4th International Conference on Materials and Metallurgical Engineering and Technology, ICOMMET 2020

A2 - Hidayat, Mas Irfan Purbawanto

A2 - Rasyida, Amaliya

PB - American Institute of Physics Inc.

T2 - 4th International Conference on Materials and Metallurgical Engineering and Technology, ICOMMET 2020

Y2 - 19 October 2020

ER -

Setianingsih T , Purwonugroho D , Mutrofin S, Rohma TN, Setianingsih T. Effect of grafting-intercalation combination toward delamination of kaoline. In Hidayat MIP, Rasyida A, editors, 4th International Conference on Materials and Metallurgical Engineering and Technology, ICOMMET 2020. American Institute of Physics Inc. 2021. 050009. (AIP Conference Proceedings). doi: 10.1063/5.0071553

Effect of grafting-intercalation combination toward delamination of kaoline

Abstract

Publication series

Conference

Keywords

Access to Document

Other files and links

Fingerprint

Cite this